Reverse osmosis treatment of condensate from ammonium nitrate production: Insights into membrane performance

Ammonium nitrate is an important fertilizer and industrial explosive. The production of ammonium nitrate entails the generation of a large volume of condensate laden with nitrogen that must be treated before environment discharge. Results in this study show that through appropriate membrane selection, over 90% rejection of ammonium nitrate can be achieved by reverse osmosis (RO) filtration. Using RO (which is highly compact and efficient) to enrich ammonium nitrate in the condensate would significantly reduce the size of the evaporation separator for ammonia recovery. The results also highlight the importance of membrane selection for this application. Results reported here suggest that a low pressure RO membrane (e.g. ESPA2) is more suitable for the dilute condensate while a high pressure RO membrane (e.g. SW30) is recommended for the concentrated condensate to ensure adequate ammonia and nitrate rejection. Ammonia and nitrate rejections were dependent on key operating parameters including applied pressure (or water flux), temperature, feed solution pH, and initial ammonium nitrate concentration in the condensate. The impact of operating conditions on ammonia and nitrate rejections was more profound for low pressure (thus high flux) than high pressure RO membrane. An extended filtration experiment shows no evidence of membrane fouling. Results from this study are useful to the integration of a compact RO system to ammonium nitrate manufacturing for pollution prevention and improving product yield. © 2021