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Novel mixed nickel/cobalt hexacyanoferrate microcubes with synergistic effects for aqueous hybrid supercapacitors

Thuy, V.V. and Hieu, N.S. and Thu, T.V. (2024) Novel mixed nickel/cobalt hexacyanoferrate microcubes with synergistic effects for aqueous hybrid supercapacitors. Dalton Transactions. ISSN 14779226

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Abstract

Combining different metals in coordination compounds is an efficient strategy to improve their various properties. Herein, mixed nickel-cobalt hexacyanoferrate (NixCoyHCF) microcubes of varying x : y molar ratios are synthesized via a co-precipitation route and comprehensively characterized to study their material and electrochemical properties. NixCoyHCF microcubes display the battery-type electrochemical energy storage mechanism in aqueous electrolytes. Among the samples, Ni1Co2HCF microcubes deliver the highest specific capacity of 134 mA h g−1 (1068 F g−1) at a specific current of 1 A g−1. This significant enhancement in the capacity indicates the synergistic and cooperative effects between Ni and Co sites in Ni1Co2HCF microcubes. The asymmetric supercapacitor device assembled with Ni1Co2HCF microcubes delivers an excellent energy density of 74.4 μW h cm−2 at a power density of 750 μW cm−2 and retains 87.7 of its initial capacity after 2000 cycles at a current density of 5 mA cm−2, indicating its robust structural integrity and electrochemical durability. This study highlights the promising potential of mixed-metal hexacyanoferrates as high-performance electrodes for aqueous supercapacitors. © 2024 The Royal Society of Chemistry.

Item Type: Article
Divisions: Offices > Office of International Cooperation
Identification Number: 10.1039/d4dt02124j
Uncontrolled Keywords: Battery storage; Cobalt; Cobalt compounds; Cobalt deposits; Coordination reactions; Coprecipitation; Molar ratio; Nickel; Nickel compounds, 'current; Cobalt hexacyanoferrate; Coordination compounds; Efficient strategy; Electrochemicals; Hybrid supercapacitors; MicroCube; Molar ratio; Property; Synergistic effect, Electrolytes
URI: http://eprints.lqdtu.edu.vn/id/eprint/11418

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